The choices in this list are an odd mix of ones that almost everyone acknowledges as top ranked and others that are likely not.

A Mathematically Perfect Redemption as the only standalone Lower Decks episode to make the cut?

No TAS classics such as Yesteryear, The Slaver Weapon or the Counterclockwise Incident?

TNG Qpid but not Q Who?

Nothing at all from Prodigy — the best effort and most successful landing of a serialized season the franchise has achieved?

Thanks for the thought experiment OP.