Comment on The Periodic Table according to astronomers

ornery_chemist@mander.xyz ⁨1⁩ ⁨week⁩ ago

• threelonmusketeers@sh.itjust.works ⁨1⁩ ⁨week⁩ ago

  Care to defend your position? Iodine is certainly not in the d-block…

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  • ornery_chemist@mander.xyz ⁨1⁩ ⁨week⁩ ago

    The intended joke is that hypervalent iodine compounds like Dess-Martin periodinane different oxidation states like you often see for transition metals. As an example, the mechanism usually drawn for oxidations by DMP is similar to those drawn for, e.g., PCC/Jones reagent, where the electrons removed from the substrate is “banked” at the metal center. Obviously, redox chemistry is not at all limited to transition metals, but I am often surprised at iodine’s propensity to engage in it. A lot of research over the past decade or two has also developed redox catalysis with these reagents, reactivity which is commonly (though again not always) the purview of transition metals.

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