The penalty shoot-out between Ajax and Panathinaikos was the longest in UEFA history with 34 kicks, surpassing the previous record of 32 from the 2007 U21 Euros

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https://www.uefa.com/uefaconferenceleague/news/0253-0d0480b11c55-28e64eff095a-1000--shoot-out-records-the-long-and-the-short-of-it/